MACROPOLYHEDRAL BORON-CONTAINING CLUSTER CHEMISTRY - CHARACTERIZATIONOF RIGID 77-ATOM [PT(B18H20)(2)](2-) DIANION ISOMERS AND AN UNUSUAL METALLABORANE HEMOPHILIC INTERACTION

Authors
MCGRATH TD JELINEK T STIBR B THORNTONPETT M KENNEDY JD
Citation
Td. Mcgrath et al., MACROPOLYHEDRAL BORON-CONTAINING CLUSTER CHEMISTRY - CHARACTERIZATIONOF RIGID 77-ATOM [PT(B18H20)(2)](2-) DIANION ISOMERS AND AN UNUSUAL METALLABORANE HEMOPHILIC INTERACTION, Journal of the Chemical Society. Dalton transactions, (15), 1997, pp. 2543-2545
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
15
Year of publication
1997
Pages
2543 - 2545
Database
ISI
SICI code
0300-9246(1997):15<2543:MBCC-C>2.0.ZU;2-S
Abstract
Reaction of [Pt(cod)Cl-2] (cod = cycloocta-1,5-diene) with [NEt4](2)[a nti-B18H20] or with [syn-B18H22] and tmnda (tmnda = N,N,N',N'-tetramet hylnaphthalene-1,8-diamine) resulted in the generation of [Pt(anti-B18 H20)(2)](2-) or [Pt(syn-B18H20)(2)](2-) dianions, for which intramolec ular steric crowding imposes rigid slab structures, and which have unu sual intimately packed anion-layer structures in their salts in the so lid state.