By means of Magnetic Circular Dichroism in X-ray Absorption Spectrosco
py we investigated the magnetic properties of fct Fe films stabilised
by epitaxial growth on the Cu(100) surface. These are compared to bcc
like Fe films. The films were characterised in situ by means of LEED,
AES and XAS for order and cleanness. Low temperature (approximate to 5
0 K) and angle dependent measurements are reported for thicknesses aro
und 3.5 (fct(5 x 1) phase) and 20 (bcc phase) monolayers. A much stron
ger MCD response is obtained from the thinner films (perpendicular mag
netisation). The MCD sum rules enabled us to determine the orbital and
spin contributions to the magnetic moment for the two phases. The res
ults are compared to theory.