O. Isnard et al., MAGNETIC CIRCULAR X-RAY DICHROISM AT THE CE L-II,L-III EDGES IN FERROMAGNETIC IRON-BASED INTERMETALLIC, Journal de physique. IV, 7(C2), 1997, pp. 439-440
Measurements of magnetic circular dichroism (MCXD) at the Ce L-II and
L-III edges have been performed from CeFe11Ti and CeFe5.5Ga6.5 both fe
rromagnetic compounds. The recorded MCXD signal is presented and compa
red to earlier reported results [1] on other intermetallic. A signific
ant magnetic moment of 5d origin has been observed, the magnitude of w
hich being very sensitive to the change in the Ce environment. An esti
mation of the 5d magnetic moment is derived from the measurements. The
observed MCXD signal is discussed at the light of macroscopic magneti
c properties that are reminded. A magnetic EXAFS of large amplitude is
observed on all the studied compound. The comparison of the MCXD spec
tra at the L-II and L-III edges shows that the signal is typical of a
mixed valence state of Ce.