The magnetization density profiles of two planar interfaces are deduce
d from polarized neutron reflectometry measurements. The first interfa
ce is the phase boundary between a thin Fe film and a MgO substrate; t
he second, a [0 0 1] twist grain boundary between two thin films of Ni
that were hot-pressed together. The atomic densities of both boundary
regions were determined to be less than those of the neighboring thin
films, while the average magnetic moments per atom were increased com
pared to the bulk films.