A clear understanding of the mechanisms of interfacial magnetic anisot
ropy rests on the structural characterisation of magnetic multilayers
which, typically, consist of two ferromagnetically coupled (F) layers
separated by a non-magnetic spacer layer. Fe/Cu/Fe trilayers are of sp
ecial interest since the coupling between the F layers of Fe changes f
rom F to antiferromagnetic depending on the thickness of the Cu spacer
layer. Here, a magnetic multilayer system, grown by molecular beam ep
itaxy (MBE), was modified by inserting Cr in the Cu: Ag(001)/8.7 Fe/3
Cu/6 Cr/3 Cu/5 Fe/10 Au where the integers refer to monolayers. Polari
zed K-edge XAFS spectra (E parallel to the substrate) were obtained fr
om fluorescence measurements in the total reflection geometry. The mul
tiple scattering paths were analysed for the Cr edge. The initial Cu g
rew pseudomorphically in a BCC structure on Fe/Ag(001). The Cr proved
to be tetragonally distorted from its BCC structure. The overlayers of
Fe on Cu are contracted by 1.27% within the plane and conserve the c
lattice parameter of Fe, though the atomic volume is contracted by 2.8
%. The Cu adopts a BCT, rather than keeping its bulk FCC, structure an
d the corresponding decrease in its atomic volume from the FCC is only
0.3%.