K. Yokota et al., HYDROGENATION OF HIGH-CONCENTRATION ARSENIC-DOPED SILICON USING RADIO-FREQUENCY HYDROGEN PLASMA, JPN J A P 1, 36(7A), 1997, pp. 4355-4358
n-type layers in silicon with high carrier concentrations have been fo
rmed by high-dose (1 x 10(15) - 1 x 10(16) cm(-2)) As-ion implantation
and subsequently 950 degrees C-annealing. The n-type layers containin
g many As clusters were exposed to radio-frequency hydrogen plasma for
30 min. While the hydrogenated samples had the same As-atom concentra
tion profile as the as-annealed samples, the carrier concentration pro
files approached the As atom concentration profile with increasing sub
strate temperature. The activation energy obtained from the Arrhenius
plot of the carrier concentration agreed well with that of the diffusi
vity of H atoms in silicon. Thus, the increase in the carrier concentr
ation is a result of H atoms reacting with As clusters.