T. Fukunaga et al., OBSERVATION OF MOLECULAR ALIGNMENT OF 3-N-OCTADECYLTHIOPHENE BY SCANNING TUNNELING MICROSCOPE, JPN J A P 1, 36(7A), 1997, pp. 4466-4467
The molecular alignment of an alkylthiophene, 3-n-octadecylthiophene,
on highly oriented pyrolytic graphite has been studied by scanning tun
neling microscopy (STM). Lateral stripes with a period of 0.42 nm and
vertical stripes with one of 5.0 nm are observed and assigned to molec
ular alignments of alkyl chains and thiophene rings connected by ''hea
d to head'', respectively. An STM image of N-n-octadecylpyrrole is als
o presented.