HYDRODYNAMIC FLUCTUATIONS, NONEQUILIBRIUM EQUATIONS OF STATE, AND THESHIFT OF THE SPINODAL LINE IN POLYMER-SOLUTIONS UNDER FLOW

Citation
M. Criadosancho et al., HYDRODYNAMIC FLUCTUATIONS, NONEQUILIBRIUM EQUATIONS OF STATE, AND THESHIFT OF THE SPINODAL LINE IN POLYMER-SOLUTIONS UNDER FLOW, Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics, 56(2), 1997, pp. 1887-1890
Citations number
16
Categorie Soggetti
Physycs, Mathematical","Phsycs, Fluid & Plasmas
ISSN journal
1063651X
Volume
56
Issue
2
Year of publication
1997
Pages
1887 - 1890
Database
ISI
SICI code
1063-651X(1997)56:2<1887:HFNEOS>2.0.ZU;2-A
Abstract
In the literature, the shift of the spinodal line of polymer solutions under Bow is attributed either to an actual shift of the spinodal due to a nonequilibrium modification of the equation of state for the che mical potential, or to an apparent shift due to an increase of hydrody namic fluctuations owing to the flow. Here we see that both approaches are compatible and that both effects add up.