M. Criadosancho et al., HYDRODYNAMIC FLUCTUATIONS, NONEQUILIBRIUM EQUATIONS OF STATE, AND THESHIFT OF THE SPINODAL LINE IN POLYMER-SOLUTIONS UNDER FLOW, Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics, 56(2), 1997, pp. 1887-1890
In the literature, the shift of the spinodal line of polymer solutions
under Bow is attributed either to an actual shift of the spinodal due
to a nonequilibrium modification of the equation of state for the che
mical potential, or to an apparent shift due to an increase of hydrody
namic fluctuations owing to the flow. Here we see that both approaches
are compatible and that both effects add up.