EQUILIBRATION OF CO(MECYCLEN)(S-ALAO)](2-[CO(MECYCLEN)(S-ALAO)](2+) ISOMERS VIA ONE-ENDED DISSOCIATION OF (S)-ALANINE() AND ANTI(ME))

Authors
BUCKINGHAM DA CLARK CR ROGERS AJ
Citation
Da. Buckingham et al., EQUILIBRATION OF CO(MECYCLEN)(S-ALAO)](2-[CO(MECYCLEN)(S-ALAO)](2+) ISOMERS VIA ONE-ENDED DISSOCIATION OF (S)-ALANINE() AND ANTI(ME)), Inorganic chemistry, 36(17), 1997, pp. 3791
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
36
Issue
17
Year of publication
1997
Database
ISI
SICI code
0020-1669(1997)36:17<3791:EOCI>2.0.ZU;2-U
Abstract
Equilibration of the syn(Me)/anti(Me) isomers of [Co(Mecyclen)(S-AlaO) ](2+) in D2O is OD- catalyzed and occurs via opening up of the (S)-ala ninato chelate and rechelation at an opposite octahedral face. This pr ocess is preferred over the usually observed OD--catalyzed epimerizati on at alpha-CHMe.