MAGNETIC-FIELD-INDUCED TRANSITION IN THE OXYGEN A-BAND

Citation
Y. Takubo et al., MAGNETIC-FIELD-INDUCED TRANSITION IN THE OXYGEN A-BAND, Journal of molecular spectroscopy, 184(1), 1997, pp. 78-83
Citations number
14
Categorie Soggetti
Spectroscopy,"Physics, Atomic, Molecular & Chemical
ISSN journal
00222852
Volume
184
Issue
1
Year of publication
1997
Pages
78 - 83
Database
ISI
SICI code
0022-2852(1997)184:1<78:MTITOA>2.0.ZU;2-B
Abstract
We investigated the magnetic-field-induced transition of the oxygen mo lecule in the region of the forbidden electronic band b(1) Sigma(g)(+) (upsilon' = 0) - X-3 Sigma(g)(-) (upsilon = 0). To detect the induced transition we used the resonant Voigt effect (magneto-optic effect in a transverse magnetic field). An elliptically polarized beam of light from a laser was frequency-tuned to the rotational lines of the band, which could be designated as the O-P(K, J) and S-R(K, J)-branch lines and the (P)Q(1, 0) line in the absence of the field. Scanning the las er frequency around the resonance frequency of these lines we measured small polarization changes caused by the Voigt effect. Comparing the measured profiles of the magnetically induced lines with the theoretic al expression for the Voigt effect we concluded that the transitions w ere induced by magnetic perturbation to the lower level triplet, which caused mixing among the X-3 Sigma(g)(-), states. (C) 1997 Academic Pr ess.