ROTATIONAL SPECTRUM OF 1,3-DIOXOLANE-ARGON

Citation
A. Maris et al., ROTATIONAL SPECTRUM OF 1,3-DIOXOLANE-ARGON, Journal of molecular spectroscopy, 184(1), 1997, pp. 145-149
Citations number
30
Categorie Soggetti
Spectroscopy,"Physics, Atomic, Molecular & Chemical
ISSN journal
00222852
Volume
184
Issue
1
Year of publication
1997
Pages
145 - 149
Database
ISI
SICI code
0022-2852(1997)184:1<145:RSO1>2.0.ZU;2-C
Abstract
The free jet millimeter wave spectrum of 1,3-dioxolane-argon has been investigated in the 60-78 GHz frequency range. The argon atom is locat ed over the center of mass of the monomer, roughly perpendicular to th e 1,3-dioxolane ring. Very high values of quartic centrifugal distorti on constants, compared to those of similar adducts, suggest a relative ly weak linkage of Ar to the ring. (C) 1997 Academic Press.