Optical emission spectroscopy with high spatial resolution was employe
d for the study of surface sputtering under reactive ion etching condi
tions in chlorine-containing gas mixtures. Secondary photon emission (
both atomic and molecular) from the processed material was found to be
strongly localized near the surface. A simple model, considering the
observed features of the secondary photon emission as induced by ion s
puttering of the processed surface, has been presented. This technique
can give new opportunities for in-situ, diagnostics and modeling of p
lasma-surface interaction in various plasma technologies.