Photodegradation of PVC films was done in simple atmosphere of air in
order to get idea about changes in PVC in an atmosphere similar to out
door exposure. The photodegradation of PVC in air shows a different UV
spectrum as compared to me degradation in nitrogen. Absorption shifts
towards smaller wavelength and the fine structure disappears. Carbony
l groups are formed the molecular weight changes with photodegradation
due to chain scission and crosslinking.