Very high amplitude nonlinear surface acoustic wave pulses with 20-100
ns duration and acoustic Mach numbers up to 0.003 were excited in fus
ed silica by nanosecond laser pulses acting on a strongly absorbing ov
erlayer. Absolute measurements were performed with a calibrated dual-p
robe-laser deflection setup. The formation of shock fronts during prop
agation and nonlinear broadening of the wave form were observed for th
e first time. Three nonlinear acoustic constants were evaluated and co
mpared with values resulting from previously measured third-order elas
tic moduli.