SULFANOLYSIS OF TRIS(2-CYANOETHYL)PHOSPHINE CHALCOGENIDES - X-RAY STRUCTURE-ANALYSIS OF OP(CH2CH2CONH2)(3) AND OP(CH2CH2CSNH2)(3)

Authors
KAMENICEK J KASPAREK F POSOLDA M BEKAREK V MAREK J
Citation
J. Kamenicek et al., SULFANOLYSIS OF TRIS(2-CYANOETHYL)PHOSPHINE CHALCOGENIDES - X-RAY STRUCTURE-ANALYSIS OF OP(CH2CH2CONH2)(3) AND OP(CH2CH2CSNH2)(3), Polish Journal of Chemistry, 71(8), 1997, pp. 1060-1065
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Polish Journal of Chemistry → ACNP
ISSN journal
01375083
Volume
71
Issue
8
Year of publication
1997
Pages
1060 - 1065
Database
ISI
SICI code
0137-5083(1997)71:8<1060:SOTC-X>2.0.ZU;2-U
Abstract
Sulfanolysis of tris(2-cyanoethyl)phosphine oxide (chalcogenide) gave new compounds of tris(2-thiocarbamoylethyl)phosphine oxide (chalcogeni de) type, alkaline hydrolysis of which afforded sodium salts of tris(2 -carboxyethyl)phosphine chalcogenides. Two compounds, OP(CH2CH2CONH2)( 3) and OP(CH2CH2CSNH2)(3) were studied by X-ray structure analysis. Th e coordination sphere around phosphorous atom is in both cases approxi mately tetrahedral.