Jk. Lee et al., SYNTHESIS AND CHARACTERIZATION OF AN ELECTROLUMINESCENT POLYESTER CONTAINING THE RU(II) COMPLEX, Chemistry of materials, 9(8), 1997, pp. 1710
A new electroluminescent polyester based on an electrochemically stabl
e polypyridylruthenium-(II) complex was prepared by the step-growth po
lymerization method. The versatility of changing its solubility by cha
nging counteranions makes it possible to prepare thin-film devices by
either spin-coating or the self-assembly technique. Single-layer LEDs
fabricated from this polymer by the spin-coating method showed bright
orange-red emission with a maximum luminance level of 300 cd/m(2). Sel
f-assembled multilayers of this material exhibit external quantum effi
ciencies close to 1%.