IRON-MODIFIED MCM-48 MESOPOROUS MOLECULAR-SIEVES

Authors
ECHCHAHED B MOEN A NICHOLSON D BONNEVIOT L
Citation
B. Echchahed et al., IRON-MODIFIED MCM-48 MESOPOROUS MOLECULAR-SIEVES, Chemistry of materials, 9(8), 1997, pp. 1716
Citations number
22
Categorie Soggetti
Chemistry Physical","Material Science
Journal title
Chemistry of materials → ACNP
ISSN journal
08974756
Volume
9
Issue
8
Year of publication
1997
Database
ISI
SICI code
0897-4756(1997)9:8<1716:IMMM>2.0.ZU;2-0
Abstract
MCM-48 mesoporous molecular sieves containing iron(III) were obtained using a direct sol-gel route followed by removal of the cetyltrimethyl ammonium hydroxide template before calcination. UV-visible, ESR, and X ANES spectroscopies show that iron mostly occupies tetrahedral sites o f the siliceous walls. The formation of oxide nanoclusters in the chan nels is favored in the presence of the organic template molecules duri ng calcination.