MEO-BIPHEP AS AN 8-ELECTRON DONOR TO RUTHENIUM(II) - CHIRAL DIALKYL COMPLEXES WITH AN UNPRECEDENTED BINDING MODE

Authors
FEIKEN N PREGOSIN PS TRABESINGER G
Citation
N. Feiken et al., MEO-BIPHEP AS AN 8-ELECTRON DONOR TO RUTHENIUM(II) - CHIRAL DIALKYL COMPLEXES WITH AN UNPRECEDENTED BINDING MODE, Organometallics, 16(17), 1997, pp. 3735-3736
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
17
Year of publication
1997
Pages
3735 - 3736
Database
ISI
SICI code
0276-7333(1997)16:17<3735:MAA8DT>2.0.ZU;2-O
Abstract
The chiral bis(3,5-di-tert-butylphenyl)phosphino MeO-Biphep complex Ru (OAc)(2)(1a), with two complexed P donors, reacts with MeLi to give Ru (Me)(2)(1a), in which only one P atom is coordinated together with an arene eta(6)-C6H3 moiety derived from one of the biaryl rings. This is an unprecedented binding mode for this type of chiral complex.