CARBONYLATION OF AMINES WITH A TUNGSTEN(IV) CARBONYL COMPLEX

Authors
MCCUSKER JE ABBOUD KA MCELWEEWHITE L
Citation
Je. Mccusker et al., CARBONYLATION OF AMINES WITH A TUNGSTEN(IV) CARBONYL COMPLEX, Organometallics, 16(17), 1997, pp. 3863-3866
Citations number
41
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
17
Year of publication
1997
Pages
3863 - 3866
Database
ISI
SICI code
0276-7333(1997)16:17<3863:COAWAT>2.0.ZU;2-Q
Abstract
Reaction of [(CO)(2)W(NPh)I-2](2) (1) with 2 equiv of piperidine yield ed (CO)(2)W(NPh)I-2(pip). In the presence of excess amine, secondary a mines (R2NH) were carbonylated to the formamides R2NCHO while primary amines (R'NH2) were converted to the ureas R'NH-CONHR'.