FORMATION OF TRIOXADAMANTANE TYPE AGLUCONES OF 3-METHOXY SECOLOGANIN DERIVATIVES

Authors
KRAJSOVSZKY G KOCSIS A SZABO LF PODANYI B
Citation
G. Krajsovszky et al., FORMATION OF TRIOXADAMANTANE TYPE AGLUCONES OF 3-METHOXY SECOLOGANIN DERIVATIVES, Tetrahedron, 53(34), 1997, pp. 11659-11668
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
53
Issue
34
Year of publication
1997
Pages
11659 - 11668
Database
ISI
SICI code
0040-4020(1997)53:34<11659:FOTTAO>2.0.ZU;2-P
Abstract
Acidic transformation of some 3,4-dihydro-3-substituted secologanin de rivatives produced trioxadamantane type compounds. The formation of th e bridged tricyclic products from monocyclic educts is interpreted as multistep hydrolysis and transacetalation accompanied by deglucosylati on. (C) 1997 Elsevier Science Ltd.