COMPLEXATION OF AROMATIC-HYDROCARBONS WITH A MACROCYCLE CONTAINING 4 TROPOLONE UNITS IN WATER

Authors
POH BL NG YY
Citation
Bl. Poh et Yy. Ng, COMPLEXATION OF AROMATIC-HYDROCARBONS WITH A MACROCYCLE CONTAINING 4 TROPOLONE UNITS IN WATER, Tetrahedron, 53(34), 1997, pp. 11913-11918
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
53
Issue
34
Year of publication
1997
Pages
11913 - 11918
Database
ISI
SICI code
0040-4020(1997)53:34<11913:COAWAM>2.0.ZU;2-M
Abstract
The stability constants EC of nine complexes formed from aromatic hydr ocarbons and the macrocycle 1 in water were measured by the transport method (H-1 nmr spectroscopy was used in the case of benzene as guest) . Their values increase with the number of aromatic rings in the aroma tic hydrocarbons. A value of -1.5 Kcal mol(-1) was obtained for the ar omatic pi-pi interaction energy at 25 degrees C. (C) 1997 Elsevier Sci ence Ltd.