A NEW ROUTE TO 1,1-DIFLUOROOLEFINS

Authors
TELLIER F BAUDRY M SAUVETRE R
Citation
F. Tellier et al., A NEW ROUTE TO 1,1-DIFLUOROOLEFINS, Tetrahedron letters, 38(34), 1997, pp. 5989-5992
Citations number
37
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
34
Year of publication
1997
Pages
5989 - 5992
Database
ISI
SICI code
0040-4039(1997)38:34<5989:ANRT1>2.0.ZU;2-V
Abstract
A new method far the synthesis of various 1,1-difluoroolefins is descr ibed. The key step is the treatment of 1-bromo-1,1-difluoro-2-alkenes with organo-metallic reagents in the presence of copper and lithium sa lts. (C) 1997 Elsevier Science Ltd.