A NEW PREPARATION METHOD OF CATALYST FOR AMMONIA-SYNTHESIS

Citation
Aw. Morawski et al., A NEW PREPARATION METHOD OF CATALYST FOR AMMONIA-SYNTHESIS, Applied catalysis. A, General, 156(1), 1997, pp. 19-27
Citations number
11
Categorie Soggetti
Chemistry Physical","Environmental Sciences
ISSN journal
0926860X
Volume
156
Issue
1
Year of publication
1997
Pages
19 - 27
Database
ISI
SICI code
0926-860X(1997)156:1<19:ANPMOC>2.0.ZU;2-T
Abstract
The preparation of a new catalyst for ammonia synthesis on the basis o f a carbon support relies on a thoroughly mixing of polyacrylonitrile (PAN) with inorganic salts Fe(NO3)(3) and KNO3 being previously dissol ved in dimethylformamid (DMF). A catalyst was reduced at the flow of N -2-H-2 mixture before activity measurements. The preparation condition s, leading to the manufacture of catalyst showing higher activity at a tmospheric pressure than an industrial iron fused catalyst, were found . The optimal composition of precursor and the temperature carbonizati on were found.