AN IMPROVED METHOD FOR CALCULATING THE EL EMENTAL COMPOSITION APPLIEDTO A SELF-INTEGRATED CARBON, HYDROGEN AND NITROGEN ANALYZER
Citation
H. Ando et al., AN IMPROVED METHOD FOR CALCULATING THE EL EMENTAL COMPOSITION APPLIEDTO A SELF-INTEGRATED CARBON, HYDROGEN AND NITROGEN ANALYZER, Bunseki Kagaku, 46(8), 1997, pp. 627-632
Categorie Soggetti
Chemistry Analytical
SICI code
0525-1931(1997)46:8<627:AIMFCT>2.0.ZU;2-B
Abstract
A carbon, hydrogen and nitrogen microanalyzer equipped with a self-int
egrated measuring system features the transportation of a combustion g
as into a cylindrical pump having a reproducible inner volume and the
collection of three signals of water, carbon dioxide and nitrogen when
the pump slowly pushes out the gas towards a series of three differen
tial thermal-conductivity cells. However, these signal intensities are
not directly proportional to the true concentration of the respective
components in the pump, because of the coexistence of foreign compone
nts other than the object. A correction of the signal intensity is the
refore needed to obtain accurate analytical results. The conventional
correction method gave rise to a minute analytical error, since the ca
lculation involved a process to roughly estimate the quantities of the
three elements in the sample being analyzed. An algebraic modificatio
n on simultaneous equations representing quantities of the three eleme
nts has resulted in the discovery of new formulae of simultaneous equa
tions by which precisely corrected analytical results can be directly
calculated, thus eliminating the need for a rough estimation of the qu
antities of the elements.