CALORIMETRIC STUDY OF THE OXYGEN BOND-ENERGY IN A BINARY V-TI CATALYST AND INDIVIDUAL VANADIUM AND TITANIUM-OXIDES

Authors
BONDAREVA VM ANDRUSHKEVICH TV PANKRATIEV YD
Citation
Vm. Bondareva et al., CALORIMETRIC STUDY OF THE OXYGEN BOND-ENERGY IN A BINARY V-TI CATALYST AND INDIVIDUAL VANADIUM AND TITANIUM-OXIDES, Reaction kinetics and catalysis letters, 61(2), 1997, pp. 337-344
Citations number
18
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
61
Issue
2
Year of publication
1997
Pages
337 - 344
Database
ISI
SICI code
0133-1736(1997)61:2<337:CSOTOB>2.0.ZU;2-X
Abstract
Bond energy of oxygen in a binary V-Ti catalyst and individual V and T i oxides has been studied by the calorimetric method. The samples stud ied were shown to be significantly different in bond energy, homogenei ty of surface oxygen and mobility of the bulk one. Vanadium and titani um oxides appeared to interact in the binary system to form an active surface with redox properties very different from those of the individ ual oxides.