A new mineral named galileiite, NaFe4(PO4)(3), has been found within t
roilite nodules in iron meteorites of the IIIA and IIIB groups. The mi
neral is optically positive (omega = 1.72, epsilon = 1.75), colorless
in transmitted light and pale amber in reflected light. Grains of gali
leiite are very small, generally 10 mu m or less; rarely, grains are u
p to 30 mu m. It is associated with Ca-free graftonite (or Ca-free sar
copside), chromite and, occasionally, schreibersite. Johnsomervilleite
may occur within troilite nodules in the same meteorite as galileiite
, but they have never been observed together in the same troilite nodu
le. Because of the small sample size, single crystal x-ray work was no
t successful; however, Gandolfi diffraction measurements were made. Th
e three strongest diffraction peaks are 2.71 Angstrom, 3.01 Angstrom a
nd 4.13 Angstrom. On the basis of its composition and similar diffract
ion pattern, it is considered to be related to johnsomervilleite, fill
owite and chladniite, all of which are rhombohedral and isostructural.
Galileiite may also be rhombohedral, but that is yet to be demonstrat
ed.