Pk. Shin et al., BIODEGRADABILITY OF DEGRADABLE PLASTICS EXPOSED TO ANAEROBIC DIGESTED-SLUDGE AND SIMULATED LANDFILL CONDITIONS, Journal of environmental polymer degradation, 5(1), 1997, pp. 33-39
The biodegradabilities of various plastics by anaerobic digested sludg
e were measured and compared with the biodegradabilities under simulat
ed landfill conditions. Bacterial poly(3-hydroxybutyrate-co-3-hydroxyv
alerate) (PHB/HV; 92/8, w/w), a natural aliphatic polyester, degraded
nearly to completion within 20 days of cultivation by anaerobic digest
ed sludge, while synthetic aliphatic polyesters such as poly-lactic ac
id, poly(butylene succinate), and poly(butylene succinate-co-ethylene
succinate) did not degrade at all in 100 days. Cellophane, which was u
sed as a control material, exhibited a similar degradation behavior to
PHB/HV. Under simulated landfill conditions, PHB/HV degraded quite we
ll within 6 months. Synthetic aliphatic polyesters also showed signifi
cant weight losses through 1 year of cultivation. The acidic environme
nt inside simulators generated by the degradation of biodegradable foo
d wastes which comprised 34% of municipal solid waste seems to cause t
he weight loss of synthetic aliphatic polyesters.