,N'-BIS(SALICYLIDENE)-1,4-DIIMINOBUTANE]COPPER(II)

Citation
Hh. Yao et al., ,N'-BIS(SALICYLIDENE)-1,4-DIIMINOBUTANE]COPPER(II), Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 1012-1013
Citations number
14
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
8
Pages
1012 - 1013
Database
ISI
SICI code
0108-2701(1997)53:<1012:,>2.0.ZU;2-Y
Abstract
In the title compound, rilomethylidyne)]diphenolato-O,N,N',O'}copper(I I), [Cu(C18H18N2O2)], the Cu atom is coordinated by an N2O2 donor set from the imine-phenol ligand in a distorted planar coordination geomet ry, with the two phenolate O atoms being deprotonated. The Cu-O bond l engths are 1.898(3) and 1.903(3) Angstrom, and the Cu-N bond lengths a re 1.941(3) and 2.000(3) Angstrom. The angles O1-Cu-N2 and O2-Cu-N1 ar e 144.0(1) and 153.3 (1)degrees, respectively. The dihedral angle betw een the two salicylaldiminato groups around the central Cu atom is 42. 7 (1)degrees.