PHOTOCHEMICAL-REACTIONS OF TRANSITION-METAL ORGANYL COMPLEXES WITH OLEFINS .18. -ETA-1,4-PENTADIENIEN-1,4-DIYL)-OXODITUNGSTEN(W-W)

Authors
KREITER CG SCHWARZ CB FRANK W REISS GJ
Citation
Cg. Kreiter et al., PHOTOCHEMICAL-REACTIONS OF TRANSITION-METAL ORGANYL COMPLEXES WITH OLEFINS .18. -ETA-1,4-PENTADIENIEN-1,4-DIYL)-OXODITUNGSTEN(W-W), Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 1018-1020
Citations number
22
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
8
Pages
1018 - 1020
Database
ISI
SICI code
0108-2701(1997)53:<1018:POTOCW>2.0.ZU;2-X
Abstract
In the binuclear title complex, [W2O(C5H5)(2)(C5H6)(CO)(2)], the W cen tres are bridged by a 1,4-pentadien-1,4-diyl ligand. The W-W distance of 2.9426 (5) Angstrom is in accord with a W-W single bond, the W-O di stance of 1.678(5) Angstrom corresponds to a W=O double bond.