(TRIS [N-(SALICYLIDENE)-2-AMINOETHYL]AMINE)TIN(IV) IODIDE ACETONITRILE SOLVATE

Authors
WATSON S ERRINGTON W FENN D MOOREN P WALLBRIDGE MGH
Citation
S. Watson et al., (TRIS [N-(SALICYLIDENE)-2-AMINOETHYL]AMINE)TIN(IV) IODIDE ACETONITRILE SOLVATE, Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 1031-1034
Citations number
20
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
8
Pages
1031 - 1034
Database
ISI
SICI code
0108-2701(1997)53:<1031:([IA>2.0.ZU;2-Y
Abstract
The crystal structure of the title compound, [Sn(C27H27N4O3)]I.0.5CH(3 )CN, involves two almost identical complex cations in the asymmetric u nit. These cations contain Sn atoms in a pseudo-octahedral environment with facial coordination of the azomethine N and the phenolate O atom s. The average Sn-O and Sn-N bond lengths are 2.048 (4) and 2.192 (5) Angstrom, respectively, while the apical N atom in the ligand is consi dered to be non-bonded at an average distance of 2.687 (5) Angstrom fr om the Sn atom.