A TETRAHYDROFURAN RING-OPENING PRODUCT - INIO]BUTOXIDO-O)-(TETRAHYDROFURAN-O)-ZIRCONIUM(IV)

Authors
POLAMO M MUTIKAINEN I LESKELA M
Citation
M. Polamo et al., A TETRAHYDROFURAN RING-OPENING PRODUCT - INIO]BUTOXIDO-O)-(TETRAHYDROFURAN-O)-ZIRCONIUM(IV), Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 1036-1037
Citations number
9
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
8
Pages
1036 - 1037
Database
ISI
SICI code
0108-2701(1997)53:<1036:ATRP-I>2.0.ZU;2-9
Abstract
The title compound, [ZrCl4(C15H18N2O)(C4H8O)], was formed via tetrahyd rofuran (thf) ring opening when ZrCl4 and 2-(phenylamino)pyridine were heated in a thf-containing reaction medium. The molecule is zwitterio nic, with distorted octahedral coordination at the negatively charged zirconium(IV) centre. A 2-(phenylamino)pyridinium cation is connected to the metal centre by a residue formed through opening of a thf ring.