TRIS(8-HYDROXYQUINOLINATO)IRON(III) ETHANOL SOLVATE

Authors
PECH L BANKOVSKY YA KEMME A LEJEJS J
Citation
L. Pech et al., TRIS(8-HYDROXYQUINOLINATO)IRON(III) ETHANOL SOLVATE, Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 1043-1045
Citations number
9
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
8
Pages
1043 - 1045
Database
ISI
SICI code
0108-2701(1997)53:<1043:TES>2.0.ZU;2-S
Abstract
The title compound, tris(8-quinolinolato-N,O)iron(III)ethanol solvate, [Fe(C9H6NO)(3)].C2H5OH, has a slightly distorted octahedral coordinat ion about the central Fe atom which bonds to the N and O atoms of each of the three 8-hydroxyquinoline ligands. The ethanol solvate molecule forms a hydrogen bond with the O atom which is least strongly bound t o Fe. The Fe-O and Fe-N bond distances are in the ranges 1.936(5)-1.99 6(5) and 2.125(6)-2.172(5) Angstrom, respectively.