A CROWN-LINKED DONOR-ACCEPTOR ASSEMBLY CONTAINING RE-I(DIIMINE)(CO)(3)CL AND NITROBENZENE COMPONENTS

Authors
ABSI M STERN CL YOON DI HUPP JT
Citation
M. Absi et al., A CROWN-LINKED DONOR-ACCEPTOR ASSEMBLY CONTAINING RE-I(DIIMINE)(CO)(3)CL AND NITROBENZENE COMPONENTS, Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 1054-1055
Citations number
12
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
8
Pages
1054 - 1055
Database
ISI
SICI code
0108-2701(1997)53:<1054:ACDACR>2.0.ZU;2-1
Abstract
The structure of the title assembly, 6,29-octaoxa-34,37-diazatetracycl o[34.3.1.1(14,18) etraconta-1(39),14,16,18(41),-31,33,35(42),36(40), 3 7-nonaene-2, 13, 19, 30-tetrone]rhenium(I), [ReCl(C32H33N3O14)(CO)(3)] , has been determined via a single-crystal diffraction study. The rhen ium ion is octahedrally coordinated. The bidentate bipyridine/crown et her/nitrobenzene assembly is folded such that the pyridyl rings and ni trobenzene moiety are almost coplanar.