Ym. Pan et Fw. Breaks, RARE-EARTH ELEMENTS IN FLUORAPATITE, SEPARATION LAKE AREA, ONTARIO - EVIDENCE FOR S-TYPE GRANITE - RARE-ELEMENT PEGMATITE LINKAGE, Canadian Mineralogist, 35, 1997, pp. 659-671
Fluorapatite is an important accessory and, locally, a major mineral i
n some extremely evolved, rare-element (Li, Rb, Cs, Be, Nb and Ta) peg
matites of the Separation Lake greenstone belt and the spatially assoc
iated S-type peraluminous granites of the Treelined Lake complex in th
e Umfreville - Conifer Lake granulite zone of the English River Subpro
vince, Ontario. The REE characteristics of fluorapatite in geochemical
ly primitive pegmatites within the Treelined Lake complex are consiste
nt with partitioning of REE with granitic melts that were derived from
crustal sources. The chondrite-normalized REE patterns of fluorapatit
e in both primary and replacement units (mainly albite-mica pods) of t
he Separation Rapids rare-element pegmatites are characterized by mark
ed discontinuities at Nd and Er. These unusual REE characteristics in
fluorapatite have been modelled based on a granitic source (i.e., the
Treelined Lake complex) and the discontinuities at Nd and Er related t
o fractionation of monazite and garnet, respectively. Fluorapatite in
the sodic wall-zones of the Separation Rapids rare-element pegmatites
contains low abundances of REE and is characterized by chondrite-norma
lized REE patterns similar to those of the host amphibolites, supporti
ng an infiltration of fluid from country rocks during the formation of
pegmatites. The occurrence of fluorapatite with similar REE character
istics, including discontinuities at Nd and Er, in a miarolitic cavity
within the Treelined Lake complex supports a genetic link between the
Separation Rapids rare-element pegmatites and the S-type peraluminous
granites associated with the granulite-facies metamorphism in the Eng
lish River Subprovince.