H. Hopf et al., METAL-CONTAINING POLY(P-XYLYLENE) FILMS BY CVD - POLY(P-XYLYLENE) WITH GERMANIUM-CRYSTALS, CHEMICAL VAPOR DEPOSITION, 3(4), 1997, pp. 197
Communication: Metal-containing polymer films are of interest for sens
or, magnetic, nonlinear optical, and catalytic applications. This comm
unication describes the preparation of poly(p-xylylene) coatings incor
porating Ge crystals from Ge-containing paracyclophane monomer. Vapor
pyrolysis of the monomer gives copolymer films with Ge fragments, whic
h are thermally decomposed to Ge crystals. This leads to an increase i
n film conductivity and there is the potential for an application as a
humidity sensor.