SYNTHESIS, CONFIGURATION AND PROPERTIES O F ESTROGENIC STEROID PORPHYRIN ENZYME MODEL COMPOUNDS

Authors
CHEN SH CHEN Y LI HG
Citation
Sh. Chen et al., SYNTHESIS, CONFIGURATION AND PROPERTIES O F ESTROGENIC STEROID PORPHYRIN ENZYME MODEL COMPOUNDS, Huaxue xuebao, 55(7), 1997, pp. 716-722
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Huaxue xuebao → ACNP
ISSN journal
05677351
Volume
55
Issue
7
Year of publication
1997
Pages
716 - 722
Database
ISI
SICI code
0567-7351(1997)55:7<716:SCAPOF>2.0.ZU;2-Y
Abstract
The model compounds of estrogenic steroid - bisporphyrins (3a) and est rogenic steroid monoporphyrin (4a) have been synthesized by the reacti on of porphyrin 1 with acyl. choride of estradiol 2 followed by insert ing of metal ion. The structures and configurations of 3a,4a,and the c orresponding precursors 3 and 4 were confirmed by UV - Vis, IR, H-1 NM R spectra and elemental analysis. The catalytic property of 3a towards oxidation of p - benzenediol was investigated.