Av. Skripov et al., NUCLEAR-SPIN-LATTICE RELAXATION IN THE ORGANIC SUPERCONDUCTOR (BEDT-TTF)(2)CU[N(CN)(2)]BR0.8CL0.2, Physics of the solid state, 39(1), 1997, pp. 32-34
The behavior of the spin-lattice relaxation rate of H-1 nuclei in the
organic superconductor (BEDT-TTF)(2)Cu[N(CN)(2)]Br0.8Cl0.2 in the temp
erature interval 12-319 K is investigated. A relaxation rate maximum,
which depends on the resonance frequency and is associated with therma
lly activated vibrations of the end ethylene groups in the BEDT-TTF mo
lecules, is observed in the vicinity of 270 K. The relaxation rate is
observed to deviate from Korringa behavior at T < 100 K. These deviati
ons can be attributed to the existence of strong antiferromagnetic spi
n correlations. (C) 1997 American Institute of Physics.