Ss. Park et al., CHARACTERIZATION OF FERROELECTRIC SRBI2TA2O9 THIN-FILMS DEPOSITED BY A RADIO-FREQUENCY MAGNETRON SPUTTERING TECHNIQUE, Journal of the Electrochemical Society, 144(8), 1997, pp. 2855-2858
Fatigue-free Bi-layer SrBi2Ta2O9 films were deposited on Pt/Ti/SiO2/Si
substrates by radio frequency magnetron sputtering. The addition of 3
0 mole percent (m/o) SrCO3 and 20 m/o Bi2O3 into the target was necess
ary in order to compensate for the lack of Sr and Bi in the films. A 2
00 nm thick Sr0.7Bi2.0Ta2.0O9 film annealed at 800 degrees C exhibited
dense morphology, a dielectric constant of 210, and a dissipation fac
tor of 0.06 at a frequency of 1 MHz. The remnant polarization 2P, and
the coercive field 2E(c) of the films were 9.1 mu C/cm(2) and 85 kV/cm
, respectively, at an applied voltage of 5 V. The leakage current dens
ity was about 7 x 10(-7) A/cm(2) at 150 kV/cm. The films showed fatigu
e-free characteristics under a +/-5 V bipolar square pulse of 1 MHz up
to 1.0 x 10(10) Hz. The SrBi2Ta2O9 films prepared by radio frequency
magnetron sputtering are attractive for application to nonvolatile mem
ory devices.