RELATION BETWEEN ACTIVITY (AND SELECTIVITY) OF CATALYTICAL SYSTEMS OFELECTROPHYLIC REACTIONS AND MEASURE (DEGREE) OF THEIR ACIDIC STRENGTH

Authors
MINSKER KS IVANOVA SR BABKIN BA ZAIKOV GE
Citation
Ks. Minsker et al., RELATION BETWEEN ACTIVITY (AND SELECTIVITY) OF CATALYTICAL SYSTEMS OFELECTROPHYLIC REACTIONS AND MEASURE (DEGREE) OF THEIR ACIDIC STRENGTH, Polymer-plastics technology and engineering, 36(5), 1997, pp. 695-702
Citations number
15
Categorie Soggetti
Polymer Sciences
Journal title
Polymer-plastics technology and engineering → ACNP
ISSN journal
03602559
Volume
36
Issue
5
Year of publication
1997
Pages
695 - 702
Database
ISI
SICI code
0360-2559(1997)36:5<695:RBA(SO>2.0.ZU;2-S
Abstract
The article discusses the relation between activity (as well as select ivity) of catalytical systems of electrophylic reactions and the measu re (degree) of their acidic strength. The efficiency of catalysts in d ifferent types of electrophylic reaction (degradation of polymers, pol ymerization of olefines, alkilation of phenoles, etc.) depend on the u niversal index of acidity, size of the charge on hydrogenation in H2O complexes and metal chlorides, and parameters of relative acidity.