SYNTHESIS OF KETONES WITH ALKYL PHOSPHONATES AND NITRILES AS ACYL CATION EQUIVALENT - APPLICATION OF DEPHOSPHONYLATION REACTION OF BETA-FUNCTIONALIZED PHOSPHONATE WITH HYDRIDE

Authors
JANG WB SHIN WS HONG JE LEE SY OH DY
Citation
Wb. Jang et al., SYNTHESIS OF KETONES WITH ALKYL PHOSPHONATES AND NITRILES AS ACYL CATION EQUIVALENT - APPLICATION OF DEPHOSPHONYLATION REACTION OF BETA-FUNCTIONALIZED PHOSPHONATE WITH HYDRIDE, Synthetic communications, 27(19), 1997, pp. 3333-3339
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
27
Issue
19
Year of publication
1997
Pages
3333 - 3339
Database
ISI
SICI code
0039-7911(1997)27:19<3333:SOKWAP>2.0.ZU;2-J
Abstract
The preparation of several alpha-substituted ketones is performed in a one-pot procedure with alkyl phosphonates and aromatic nitriles by su bsequent treatment of LiAlH4. A new method for nitriles used as an acy l cation equivalent is described.