OXIDATION, OF STEROIDAL 5-EN-3-BETA-OL WITH PYRIDINIUM CHLOROCHROMATE- ISOLATION OF KEY INTERMEDIATE, STEROIDAL 6-BETA-HYDROXY-4-EN-3-ONE

Authors
KORDE SS UDASI RA TRIVEDI GK
Citation
Ss. Korde et al., OXIDATION, OF STEROIDAL 5-EN-3-BETA-OL WITH PYRIDINIUM CHLOROCHROMATE- ISOLATION OF KEY INTERMEDIATE, STEROIDAL 6-BETA-HYDROXY-4-EN-3-ONE, Synthetic communications, 27(19), 1997, pp. 3419-3430
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
27
Issue
19
Year of publication
1997
Pages
3419 - 3430
Database
ISI
SICI code
0039-7911(1997)27:19<3419:OOS5WP>2.0.ZU;2-#
Abstract
The PCC oxidation of 5-en-3 beta-ol steroids proceeds to 4-en-3,6-dion e through the intermediate 5-en-3-one. The isolation of another key in termediate, steroidal 6 beta-hydroxy-4-en-3-one guides an understandin g of the mechanism involved.