Hw. Schleibinger et al., THE SICK BUILDING SYNDROME AND HVAC SYSTE MS - MVOC FROM AIR FILTERS, Zentralblatt fur Hygiene und Umweltmedizin, 200(2-3), 1997, pp. 137-151
Growth and emissions of volatile metabolites of microorganisms on air
filters are suspected to contribute to health complaints in ventilated
rooms. To prove the microbiological production of volatile organic co
mpounds (MVOC), concentrations of aldehydes and ketones were determine
d in two large HVAC systems. The in situ derivated aldehydes and keton
es (as 2,4-dinitrophenyl-hydrazones) were analysed by HPLC and UV dete
ction. The detection limit of each compound was 1 ppb (margin of error
< 10%). Field measurements were carried out before and after the pref
ilters and the main filters, respectively, to investigate whether alde
hydes and ketones increase in concentration after filters of HVAC syst
ems. First results show that the compounds formaldehyde, acetaldehyde
and acetone could be detected before and after the filters. The concen
trations of these VOC after the filters were significantly increased -
as a mean over twenty measurements -, especially as far as filters ma
de of glass fibre are concerned. However the found concentrations were
low and mostly comparable to outdoor findings. In simultaneous labora
tory experiments pieces of used filter material of one HVAC system and
unused filter pieces (for blank values) were examined in small incuba
tion chambers to investigate the possible production of MVOC. For the
incubation a temperature of 20 degrees C and a relative humidity of 95
% was chosen. In these experiments an almost identical spectrum of com
pounds (formaldehyde and acetone) was found as in the field measuremen
ts. The concentrations of these compounds were higher in the chambers
with the used filter pieces. The concentration of acetone ranged up to
almost 12 mg/m(3). - As our field experiments correspond with our lab
oratory experiments, we assume that the microbial production of volati
le organic compounds in HVAC systems under operating conditions is pos
sible.