PREPARATION OF MOLDING RESINS FROM INEXPENSIVE BY-PRODUCTS .2. PROPERTIES OF MOLDINGS MADE WITH VARIOUS CATALYZED PHENOLATED AND UNMODIFIEDPITCH LIGNIN SYSTEMS/
Re. Ysbrandy et al., PREPARATION OF MOLDING RESINS FROM INEXPENSIVE BY-PRODUCTS .2. PROPERTIES OF MOLDINGS MADE WITH VARIOUS CATALYZED PHENOLATED AND UNMODIFIEDPITCH LIGNIN SYSTEMS/, Cellulose Chemistry and Technology, 31(3-4), 1997, pp. 213-226
A previous study(1) indicated that the properties of 25 and 50% resin
mouldings prepared from pitch and lignin via acid or alkaline phenolat
ion (mass ratio 60:40) were not inferior to resins from pitch and lign
in made according to the conventional route of novolac manufacture (vi
a a formaldehyde stage). It was also evident from a supporting study(2
) that incorporation of relatively small amounts of unmodified lignin
into phenol novolac mouldings of 25% resin content reduced the physica
l properties of the mouldings significantly. Ln the present study, cer
tain catalyst systems were used in the phenolation process of pitch an
d lignin and the products were further investigated for their properti
es as moulding resins.