The formation of Gd/Cr interface, the growth mechanism and electronic
structure of Gd overlayers were investigated by synchrotron radiation
photoemission. It is shown that Gd adatoms interact with the Cr substr
ate weakly. A lower deposition rate of the Gd overlayer (1.0 Angstrom/
min) favors the smooth growth of Gd/Cr interface. However, higher depo
sition rate (6.0 Angstrom/min) leads to the cluster growth of the Gd o
verlayer and the presence of a ''two-peak'' feature of Gd 4f emission.
We correlate this feature with the different coordination number of s
urface atoms derived from cluster-induced surface roughness.