BERYLLIUM DICHLORIDE - EFFICIENT PROMOTER FOR THE ADDITION OF ORGANOLITHIUMS AND ORGANOMAGNESIUMS TO CYCLOHEXEN-2-ONE

Authors
KRIEF A DEVOS MJ DELOMBART S BOSRET J COUTY F
Citation
A. Krief et al., BERYLLIUM DICHLORIDE - EFFICIENT PROMOTER FOR THE ADDITION OF ORGANOLITHIUMS AND ORGANOMAGNESIUMS TO CYCLOHEXEN-2-ONE, Tetrahedron letters, 38(35), 1997, pp. 6295-6298
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
35
Year of publication
1997
Pages
6295 - 6298
Database
ISI
SICI code
0040-4039(1997)38:35<6295:BD-EPF>2.0.ZU;2-J
Abstract
Organoberyllium compounds, generated by transmetallation from Grignard and organolithium reagents react with 2-cyclohexenone to give predomi nantly the adducts resulting from conjugated addition. The chemoselect ivity of this reaction was found to be highly dependent upon the natur e of organic moiety and of the conditions used. (C) 1997 Published by Elsevier Science Ltd.