THE COORDINATION MODE OF TRI(2-PYRIDYL) METHANOL TO RHODIUM(III)

Authors
ADOLFSSON H CERNERUD M MOBERG C
Citation
H. Adolfsson et al., THE COORDINATION MODE OF TRI(2-PYRIDYL) METHANOL TO RHODIUM(III), Inorganica Chimica Acta, 262(1), 1997, pp. 65-67
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
262
Issue
1
Year of publication
1997
Pages
65 - 67
Database
ISI
SICI code
0020-1693(1997)262:1<65:TCMOTM>2.0.ZU;2-Y
Abstract
The coordinational preference of tri(2-pyridyl)methanol to rhodium(III ) was investigated. Two different methods were used for the preparatio n of complexes. Starting either from Rh(I) in chloroform or from Rh(II I) led to the same final complex, in which the ligand coordinates to t he rhodium ion in a symmetrical N,N',N '' fashion, although, in the la tter case, the intermediate formation of an unsymmetrical isomer was o bserved.