THE FIRST SILA-BRIDGED DICYCLOPENTADIENYL DIRUTHENIUM COMPLEX - SYNTHESIS AND X-RAY STRUCTURE OF (ME2SI)[(ETA(5)-C5H4)RU(CO)](2)(MU-CO)(2)

Authors
ZHOU XZ ZHANG YQ XU SS TIAN GL WANG BQ
Citation
Xz. Zhou et al., THE FIRST SILA-BRIDGED DICYCLOPENTADIENYL DIRUTHENIUM COMPLEX - SYNTHESIS AND X-RAY STRUCTURE OF (ME2SI)[(ETA(5)-C5H4)RU(CO)](2)(MU-CO)(2), Inorganica Chimica Acta, 262(1), 1997, pp. 109-112
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
262
Issue
1
Year of publication
1997
Pages
109 - 112
Database
ISI
SICI code
0020-1693(1997)262:1<109:TFSDDC>2.0.ZU;2-E
Abstract
Thermal treatment of a solution of Ru-3(CO)(12) and C5H5Me2SiC5H5 in h eptane gives (Me2Si) [(eta(5)-C5H4)Ru(CO)](2)(mu-CO)(2) (1) in good yi eld. An investigation on the infrared spectra of 1 in KBr disc and CH2 Cl2 solution reveals the coexistence of two isomers la (bridging form) and 1b (non-bridging form), with the former dominant. The molecular s tructure of 1a has been determined by X-ray diffraction.