CHARGE-TRANSFER COMPLEX OF A NEW ACCEPTOR CYANANILATE WITH TETRAMETHYLTETRATHIAFULVALENE, (TMTTF)(2)HCNAL

Authors
ZAMAN MB MORITA Y TOYODA J YAMOCHI H SAITO G YONEYAMA N ENOKI T NAKASUJI K
Citation
Mb. Zaman et al., CHARGE-TRANSFER COMPLEX OF A NEW ACCEPTOR CYANANILATE WITH TETRAMETHYLTETRATHIAFULVALENE, (TMTTF)(2)HCNAL, Chemistry Letters, (8), 1997, pp. 729-730
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
8
Year of publication
1997
Pages
729 - 730
Database
ISI
SICI code
0366-7022(1997):8<729:CCOANA>2.0.ZU;2-J
Abstract
Cyananilic acid (H(2)CNAL) gave a charge-transfer complex with tetrame thyltetrathiafulvalene, (TMTTF)(2)HCNAL, in which the acceptor forms a hydrogen-bonded ribbon arrangement and the donor forms a columnar sta cking. The ionicity of the donor is estimated as +0.5. The electrical conductivity is 0.03 Scm(-1) with the activation energy of 0.05 eV. Th e magnetic spin susceptibility is described in terms of a one-dimensio nal antiferromagnet.