4,5-DIIODO-4',5'-ETHYLENEDIOXYTETRATHIAFULVALENE AND ITS METALLIC RADICAL SALTS

Authors
KUWATANI Y OGURA E NISHIKAWA H IKEMOTO I IYODA M
Citation
Y. Kuwatani et al., 4,5-DIIODO-4',5'-ETHYLENEDIOXYTETRATHIAFULVALENE AND ITS METALLIC RADICAL SALTS, Chemistry Letters, (8), 1997, pp. 817-818
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
8
Year of publication
1997
Pages
817 - 818
Database
ISI
SICI code
0366-7022(1997):8<817:4AIMR>2.0.ZU;2-K
Abstract
4,5-Diiodo-4',5'-ethylenedioxy-TTF (EDO-TTFI2) was synthesized in mode rate yield by the reaction of EDO-TTF with LDA, followed by quenching with CF3(CF2)(5)I Although EDO-TTF contains electron-withdrawing iodin e as the substituent, this compound has a similar donor ability to BED T-TTF. The radical-cation salt (EDO-TTFI2)(2) . ClO4 shows a metallic conductivity down to 50 K, reflecting the strong I ... O interaction.