Bk. Miremadi et al., A MOLYBDENUM-DISULFIDE MAGNETIC SOLID LUBRICANT FOR FERROMAGNETIC SURFACES, Journal of applied physics, 82(5), 1997, pp. 2636-2639
Molybdenum disulfide (MoS2) has been used ill industrial applications
as a dry lubricant. Although this material initially improves anti-wea
r properties, as surfaces move against each other the lubricating part
icles tend to spread out from the asperity points, To reduce this spre
ad of lubricant, MoS2 platelets were made magnetic by replacing the un
saturated or loosely bonded sulfur atoms (located mainly on the edges
of Ore platelets) with magnetic elements such as Fc, Ni, or Co particl
es. Under appropriate experimental conditions these elements form stab
le bonds with the partially free Mo atoms of the edges and are protect
ed from oxidation in air by the basal planes of the overlapping neighb
oring layers. When compared to the friction coefficient of pure MoS2,
the incorporation of magnetic Fe particles for example, increases the
friction depending on The Fe/Mo ratio, but the overall result is in an
improved lubricant with unique magnetic properties when the Fe/Mo rat
io is properly optimized. In this application at least one of the surf
aces must be ferromagnetic to hold the lubricant in place. (C) 1997 Am
erican Institute of Physics.